It's rare to find a MUD that will hire someone who's not at least had prior experience playing said game. My advice to you is to look for a game that you like playing and wait until the time when they're hiring new staff. I know I didn't set out to end up on the staff of the MUD I was on. I played it from beta and one day got an email asking if I'd like to join staff. To ensure the quality of the people they hire, most MUDs like to see your capabilities before giving you positions of authority/responsibility.
Take care,
Jason
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